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Q. Cope reaction is

CMC MedicalCMC Medical 2015

Solution:

Cope reaction is $ {{E}_{2}} $ intra-molecular. ? Cope elimination is a syn-elimination and proceeds through a cyclic transition state. ? The negatively charged oxygen of the amine oxide is the base that remove a proton from $ \beta \text{-} $ carbon. ? Because the nucleophiles and leaving group are in same molecule, this is an intra-molecular $ {{E}_{2}} $ reaction and give less substituted alkene as the major product.

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