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Q. Coordination number of Cr is six. A complex ion of Cr with $C_2O_4^{ 2-}$, en and superoxide ion, $O_2^ -$ has the formula $[Cr(C_2O_4)_x(en)_y(O_2)_z]^-$. The ratio x : y : z will be

Coordination Compounds

Solution:

x : y : z should be such that total charge = -1(i.e. charge on the complex ion).
For (a), total charge = + 3 + 1 (-2) + 1(0) + 1 (-1) = 0
For (b), total charge = + 3 + 1 (-2) + 1(0) + 2(-1) = -1
Hence, (b) is correct.