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Q. Consider the following reaction
$N _{2} O _{4}( g ) \rightleftharpoons 2 NO _{2}( g ) ; \Delta H ^{0}=+58 \,kJ$
For each of the following cases $(a, b),$ the direction in which the equilibrium shifts is:
(a) Temperature is decreased
(b) Pressure is increased by adding $N _{2}$ at constant $T$

JEE MainJEE Main 2020Equilibrium

Solution:

$\Delta H ^{\circ}>0 \quad T \downarrow$ equation shifts back ward.

$N _{2}$ is treated as inert gas in this case hence no effect on equilibrium