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Q. Consider the following halogen-containing compounds:
I. $CHCl _{3}$
II. $CCl _{4}$
III. $CH _{2} Cl _{2}$
IV. $CH _{3} Cl$
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The compounds with a net zero dipole moment are:

Haloalkanes and Haloarenes

Solution:

In (II) and (V), the dipole vectors are cancelled, so there is zero dipole moment.