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Q. Consider the following :
A. Sodium acetate
B. Acetic acid + Sodium acetate
C. Acetic acid
The pH of their equimolar aqueous solutions will be such that :

Equilibrium

Solution:

$A \rightarrow CH _{3} COONa \rightarrow$ Salt (aq. solution basic)
$B \rightarrow CH _{3} COOH / CH _{3} COONa$
$\rightarrow pH .$ of acidic buffer
$C \rightarrow CH _{3} COOH \rightarrow$ weak acid
$A > B > C$