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  4. Compounds [ PtCl 2( NH 3)4] Br 2 and [ PtBr 2( NH 3)4] Cl 2 shows the following type of isomerism:

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Q. Compounds $\left[ PtCl _{2}\left( NH _{3}\right)_{4}\right] Br _{2}$ and $\left[ PtBr _{2}\left( NH _{3}\right)_{4}\right] Cl _{2}$ shows the following type of isomerism:

Coordination Compounds

Solution:

Because they furnish different ion in solution.

$\left[ PtCl _{2}\left( NH _{3}\right)_{4}\right] Br _{2} \rightleftharpoons\left[ Pt Cl _{2}\left( NH _{3}\right)_{4}\right]^{2+}+2 Br^-$

$\left[ PtBr _{2}\left( NH _{3}\right)_{4}\right] Cl _{2} \rightleftharpoons\left[ Pt Br _{2}\left( NH _{3}\right)_{4}\right]^{2+}+2 Cl ^{-}$