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Q. Coefficient of linear expansion of a vessel completely filled with $Hg$ is $1 \times 10^{-5} /{ }^{\circ} C$. If there is no overflow of $Hg$ on heating the vessel, then coefficient of cubical expansion of $Hg$ is

Thermal Properties of Matter

Solution:

Expansion in $Hg$ volume $\leq$ expansion in container.
$\Rightarrow $ Volume coefficient of $Hg \leq 3 \times$ Linear coefficient of expansion of vessel
$ \leq 3 \times 1 \times 10^{-5} /{ }^{\circ} C $
$ \gamma_{H g} \leq 3 \times 10^{-5} /{ }^{\circ} C$