$Cl_2O_7$ is the anhydride of $HClO_4$. It reacts with water slowly to give perchloric acid
$Cl_2O_7 + H_2 O \to \underset{\text{Perchlororic acid}}{2HClO_4}$
Its structure is as follows
It is less reactive than other oxides of chlorine and does not react with $P, S$, coal or paper at room temperature.