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Q. Choose the correct acidity order of the following phenols.

KEAMKEAM 2005Alcohols Phenols and Ethers

Solution:

Electron attracting substituents like $- X $ or $-NO_2$ increase the acidity of phenol and eiectron releasing substituents like $- CH_3$ decrease the acidity. So, o-nitrophenol is the strongest acid in the given compounds. The correct order of acidity is o-nitrophenol > p-chlorophenol > phenol > p-cresol