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Q. $\ce{CH3CHO + HCHO ->[Dil.\, NaOH][\text{Heat}] A }$
$\ce{->[HCN][H_3O^+] B}$
The structure of the compound $B$ is

UPSEEUPSEE 2013

Solution:

$CH_3CHO+HCHO \ce{ ->[{dil.NaOH}][{\text{cross aldol condensethem}}] }$

$\underset{\text{3-hydroxy propanal}}{{HOCH_2-CH_2-CHO}}$

$\ce{ ->[{\text{Heat}}][{-H_2O}] }\underset{\text{prop-2-enal (A)}}{{CH_2=CH-CHO}}$

$\ce{ ->[{HCN}][{\text{1, 2, addition}}] }$ image

image