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Q. Calculate the $pOH -p K_{ b }$ for the buffer, $0.20 \,M \,NH _{3}$, $0.40 \,M \,NH _{4} \,Cl , K_{ b }$ for ammonia $=10$

Equilibrium

Solution:

$pOH =p K_{ b }+\log \frac{[\text { Salt }]}{[\text { Base }]}$
$pOH -p K_{ b }=\log \frac{0.4}{0.2}=0.30$