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Q. Calculate the equivalent weight of $KHC _{2} O _{4}$ when it is neutralised by KOH.

Redox Reactions

Solution:

$KHC _{2} O _{4} \rightleftharpoons K ^{+}+ HC _{2} O _{4}^{-} \rightleftharpoons H ^{+}+ C _{2} O _{4}^{2-}$

$KOH \rightleftharpoons K ^{+}+ OH ^{-}$

There is one replaceable $H$ in $KHC _{2} O _{4},$ so its $n$ - factor is

1. Its eq. wt $=\frac{128}{1}=128$.