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Q. Calculate $\Delta G^{\circ}$ for conversion of oxygen to ozone, $\frac{3}{2} O _{2}( g ) \longrightarrow O _{3}(g)$ at $298\, K$, if $K_{p}$ for this conversion is $ 2.47\times 10^{-29}$ .

Punjab PMETPunjab PMET 2011Thermodynamics

Solution:

$\Delta G^{\circ} =-2.303 R T \log K_{p}$
$\Delta G^{\circ} =-2.303 \times(8.314) \times(298)$
$\left(\log 2.47 \times 10^{-29}\right)$
$\Delta G^{\circ} =163000\, J\, mol ^{-1}$
$=163\, kJ\, mol ^{-1}$