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  4. Both [ Ni ( CO )4] and [ Ni ( CN )4]2- are diamagnetic. The hybridization of nickel in these complexes, respectively, are

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Q. Both $\left[ Ni ( CO )_{4}\right]$ and $\left[ Ni ( CN )_{4}\right]^{2-}$ are diamagnetic. The hybridization of nickel in these complexes, respectively, are

JEE AdvancedJEE Advanced 2008

Solution:

$Ni ( CO )_{4}= sp ^{3}$
$\left.Ni ( CN )_{4}\right]^{2-}= dsp ^{2}$