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Chemistry
Bond order of N2+,N2- and N2 will be
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Q. Bond order of $N_{2}^{+},N_{2}^{-}$ and $N_{2}$ will be
NEET
NEET 2022
Chemical Bonding and Molecular Structure
A
$2.5,2.5$ and $3$ respectively
66%
B
$2,2.5$ and $3$ respectively
24%
C
$3,2.5$ and $3$ respectively
7%
D
$2.5,2.5$ and $2.5$ respectively
4%
Solution:
$N_{2}^{+} (13):\left(\sigma 1s^{2}\right)\left(\sigma^* 1s^{2}\right)\left(\sigma 2s^{2}\right)\left(\sigma^* 2s^{2}\right)\left(\pi 2p_{x}^{2} = \pi2p_{y}^{2}\right)\left(\sigma 2p_{z}^{1}\right)$
$B .O. = \frac{1}{2} \times (9 - 4) = 2.5$
$N_{2}^{-}(15) : \left(\sigma 1s^{2}\right)\left(\sigma^* 1s^{2}\right)\left(\sigma 2s^{2}\right)\left(\sigma^* 2s^{2}\right) \left(\pi 2p_{x}^{2} = \pi2p_{y}^{2}\right)$
$\left(\sigma 2p_{z}\right)^{2} \left(\pi^ * 2p_{x}^{1}\right)$
$B .O. = \frac{1}{2}\times (10-5 )= 2.5$
$N_{2}(14) : \left(\sigma 1s^{2}\right)\left(\sigma^* 1s^{2}\right)\left(\sigma 2s^{2}\right)\left(\sigma^* 2s^{2}\right) \left(\pi 2p_{x}^{2} = \pi2p_{y}^{2}\right)$
$\left(\sigma 2p_{z}^{2}\right)$
$B .O. = \frac{1}{2}\times (10-4 )= 3.0$