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Chemistry
Based on the first law of thermodynamics, which one of the following is correct?
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Q. Based on the first law of thermodynamics, which one of the following is correct?
NTA Abhyas
NTA Abhyas 2020
Thermodynamics
A
For an isochoric process, $\text{ΔE} \, \text{=} \, - \text{q}$
21%
B
For an adiabatic process, $\text{ΔE} \, \text{=} \, - \text{w}$
18%
C
For an isothermal process, $\text{q} = \text{W}$
24%
D
For a cyclic process, $\text{q} = - \text{W}$
38%
Solution:
(a) For isochoric process, $\text{ΔV} \, \text{=} \, \text{0}$
$\text{W} \, \text{=} \, \text{pΔV} \, \text{=} \, \text{0}$
$\therefore \, \text{ΔE} \, \text{=} \, \text{q}$
(b) For adiabatic process, $q=0$
$\text{ΔE} \, \text{=} \, \text{W}$
(c) For isothermal process, $\text{ΔT} \, \text{=} \, \text{0}$
and $\text{ΔE} \, \text{=} \, \text{0}$
$\text{q} \, \text{=} \, - \text{W}$
(d) For cyclic process, state functions like
$\text{ΔE} \, \text{=} \, \text{0}$
$\text{q} \, \text{=} \, - \text{W}$