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Q. At $550\, K$, the $K_{c}$ for the following reaction is $10^{4} mol ^{-1} L$
$X_{(g)}+Y_{(g)} \rightleftharpoons Z_{(g)}$
At equilibrium, it was observed that
$[X]=\frac{1}{2}[Y]=\frac{1}{2}[Z]$
What is the value of $[Z]$ (in $mol L ^{-1}$ ) at equilibrium?

Equilibrium

Solution:

Let $[X]=\frac{1}{2}[Y]=\frac{1}{2}[Z]=x$

then $[Y]=2 x$ and $[Z]=2 x,[X]=x$

Now, $K=\frac{[Z]}{[X][Y]} $

$\Rightarrow 10^{4}=\frac{2 x}{x \times 2 x}$

$ \Rightarrow x=10^{-4}$

$\therefore [Z]=2 x=2 \times 10^{-4}$