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Q. At $527^{\circ} C$, the reaction given below has $K _{c}=4$
$NH _{3}( g ) \rightleftharpoons \frac{1}{2} N _{2}( g )+\frac{3}{2} H _{2}( g )$
What is the $K _{ p }$ for the reaction?
$N _{2}( g )+3 H _{2}( g ) \rightleftharpoons 2 NH _{3}( g )$

Equilibrium

Solution:

If, $K_{c}=\frac{\left[N_{2}\right]^{1 / 2}\left[H_{2}\right]^{3 / 2}}{\left[N H_{3}\right]^{1}}=4$

then $\frac{\left[ NH _{3}\right]^{2}}{\left[ N _{2}\right]\left[ H _{2}\right]^{3}}=(4)^{-2}=\frac{1}{16}$

also $K_{p}=K_{c} \cdot(R T)^{\Delta n_{g}}$