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Chemistry
Assuming 2s-2p mixing is NOT operative, the paramagnetic species among the following is
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Q. Assuming $2s-2p$ mixing is NOT operative, the paramagnetic species among the following is
Chemical Bonding and Molecular Structure
A
$Be_2$
10%
B
$B_2$
8%
C
$C_2$
79%
D
$N_2$
4%
Solution:
as it has two unpaired electrons
$Be_2 = \sigma 1s^2 \sigma^* 1s^2, \sigma2s^2 \sigma^* 2s^2$
$B_2 = \sigma 1s^2 \sigma^* 1s^2, \sigma2s^2 \sigma^* 2s^2 \sigma 2p_z^2$
$C_2 = \sigma 1s^2 \sigma^* 1s^2, \sigma2s^2 \sigma^* 2s^2 \sigma 2p_z^2 \pi 2p_x^1 \pi 2p_y^1$
$N_2 = \sigma 1s^2 \sigma^* 1s^2, \sigma2s^2 \sigma^* 2s^2 \sigma 2p_z^2 \pi 2p_x^2 \pi 2p_y^2$