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Q. Assertion : When $KI$ solution is added to $AgNO_{3}$ solution, negatively charged sol results.
Reason: Negative charge of sol is due to preferential adsorption of iodide ions from the dispersion medium.

Surface Chemistry

Solution:

When $KI$ solution is added to $AgNO_{3}$ solution, positively charged sol results due to adsorption of $Ag^{+}$ ions from dispersion medium.
$Agl/Ag^{+}$
Positively charged