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Q.
Assertion: Toluene in presence of UV rays forms benzaldehyde. Reason: Dichlorotoluene is formed as an intermediate.
AIIMSAIIMS 2011Aldehydes Ketones and Carboxylic Acids
Solution:
Oxidation of toluene using $CrO _{3}$ in acetic anhydride or $CrO _{2} Cl _{2}$ in $CCl _{4}$ or $CS _{2}$ and then hydrolysis gives benzaldehyde. No such intermediate is formed.