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Q. Assertion : The solutions which show large positive deviations from Raoult’s law form maximum boiling azeotropes.
Reason : $95\%$ aqueous solution of ethanol is maximum boiling azeotrope.

Solutions

Solution:

The solutions which show a large positive deviation from Raoults law form minimum boiling azeotrope, and $95\%$ ethanol solution is minimum boiling azeotrope.