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Q. Assertion : The maximum number of electrons in the shell with principal quantum number $n$ is equal to $2n^{2}$.
Reason : Two electrons can have the same value of three quantum numbers $n,l$ and $m_{b}$ but must have the opposite spin quantum number.

Structure of Atom

Solution:

In $n ^{\text {th }}$ shell, the total number of orbitals are $n ^{2}$ where each orbital can occupy a maximum of two electrons with opposite spin quantum number as $+1 / 2$ and $-1 / 2$.
Rest of the three quantum numbers in a given orbital will be same.
Thus it will follow Pauli's exclusion principle.
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion