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Q. Assertion :Sodium carbonate extract of a salt containing sulphide ions gives a violet colour with appropriate reagent.
Reason : The reagent sodium nitroprusside gives violet colour due to the formation of sodium thionitroprusside.

AIIMSAIIMS 2012

Solution:

$Na _{2} S + Na _{2}\left[ Fe ( NO )( CN )_{5}\right] \longrightarrow \underset{\text{violet}}{Na _{4}\left[ Fe ( NOS )( CN )_{5}\right]}$