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Q. Assertion: Manganese (atomic number $25$) has a less favourable electron affinity than its neighbours on either side because
Reason: The manganese has stable, $[Ar]^{18} 3d^5 4s^2$ electrons configuration

Classification of Elements and Periodicity in Properties

Solution:

The magnitude of an element’s electron affinity depends on the element’s valence shell electrons configuration.
${ }_{25} Mn =[ Ar ]^{18} 3 d ^{5} 4 s ^{2}$ configuration, ${ }_{24} Cr =[ Ar ]^{18} 3 d ^{5} 4 s ^{1}$ configuration, ${ }_{26} Fe =[ Ar ]^{18} 3 d ^{6} 4 s ^{2}$ configuration