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Q. Assertion : Magnetic moment of $Mn^{2+}$ is less than that of $Cr^{2+}$.
Reason : Higher the atomic number smaller is the magnetic moment.

The d-and f-Block Elements

Solution:

The magnetic moment is determined by number of unpaired electrons and is calculated by using the formula, $\mu = \sqrt{n\left(n+2\right)}$ where n is number of unpaired electrons.
It increases with increase in number of unpaired electrons hence $Mn^{2+}$ will have higher magnetic moment than $Cr^{2+}$.