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Q. Assertion : $K_2Cr_2O_7$ is used as primary standard in volumetric analysis.
Reason : It has a good solubility in water.

AIIMSAIIMS 2006The d-and f-Block Elements

Solution:

Potassium dichromate is used in volumetric analysis mostly in oxidation titration because it is not deliquescent. It forms compound with other elements and precipitate out. So the assertion is true but the reason is false.