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Q. Assertion: $CuSO_{4}.5H_{2}O$ has one hydrogen-bonded molecule of water.
Reason: The four molecules of water are coordinated in $CuSO_{4}. 5H_{2}O$.

Hydrogen

Solution:

There is 5 crystal water present in $5 H _{2} O$. There are five water molecule present in the crystal framework of the molecule among which 4 water molecules are attached to $Cu ^{+2}$ and 1 hydrogen-bonded molecule is attached to $SO _{4}^{2}$
$\left[ Cu \left( H _{2} O \right)_{4}\right]^{2+} SO _{4}^{2-} \cdot H _{2} O .$