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Q. Assertion: Copper liberates hydrogen from a solution of dilute hydrochloric acid.
Reason: Hydrogen is below copper in the electrochemical series.

AIIMSAIIMS 1995Redox Reactions

Solution:

Cu cannot liberate $H_2$ from a solution of dilute HCl as hydrogen is above copper in the electrochemical series.

$E^{\circ}_{\,\,H^{+}/½H_{2}} = \pm \,0.00$

$E^{\circ}_{\,\,Cu^{2+} /Cu} = +0.34$