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Q. Assertion : As work function of a material increases by some mechanism, it requires greater energy to excite the electrons from its surface.
Reason : A plot of stopping potential (Vs) versus frequency ($\upsilon$) for different metals, has greater slope for metals with greater work functions.

AIIMSAIIMS 2017Dual Nature of Radiation and Matter

Solution:

As $eV_{s}=h\upsilon-W$
$V_{s}=\left(\frac{h}{e}\right)\upsilon-\left(\frac{W}{e}\right)$
For $V_{s}$ versus \upsilon graph, slope = $\frac{h}{e}$ = constant.