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Q. Assertion : $Al$ forms $[AlF_6]^{3-}$ but B does not form $[BF_6]^{3-}$.
Reason : $B$ does not react with $F_2$.

AIIMSAIIMS 2018The p-Block Elements

Solution:

$B$ does not have vacant $d$ -orbitals (sub-shell) as its valence shell.