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Q. Assertion (A) Tertiary butylamine can be prepared by the action of $NH _{3}$ on tert-butylbromide.
Reason (R) Tertiary butylbromide being $3^{\circ}$ alkylhalide prefers to undergo elimination on the treatment with a base.

Amines

Solution:

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tert-butyl bromide prefer to undergo elimination rather than substitution on treatment with a base. The product is iso-butylene rather than tert-butylamine.