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Q. Assertion (A) s-orbital electron will be more tightly bound to the nucleus than p-orbital electron.
Reason (R) Zeff  experienced by the electron decreases with increase of azimuthal quantum number (l).

Structure of Atom

Solution:

s-orbital electron will be more tightly bound to the nucleus than p-orbital electron. Zeff  experienced by the electron decreases with increase of azimuthal quantum number (l).
Thus, both A and R are correct but R is not the correct explanation of A.