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Q. Assertion (A) Element with electronic configuration $[ Ar ] 4 s^{2} 3 d^{5}$ is a $d$ - block element.
Reason (R) The last electron enters the $d$-orbital.

Classification of Elements and Periodicity in Properties

Solution:

Element with electronic configuration $=[ Ar ] 4 s^{2} 3 d^{5}$ (manganese) is a $d$-block element because last electron enters the $d$-orbital.
Thus, both $A$ and $R$ are correct and $R$ is the correct explanation of $A$.