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Q. Arrange the following halides in the decreasing order of $ {{S}_{N}}1 $ reactivity. $ C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}Cl, $ $ C{{H}_{2}}=CHCH(Cl)C{{H}_{3}}, $ $ (I) $ $ (II) $ $ C{{H}_{3}}c{{H}_{2}}CH(Cl)C{{H}_{3}} $ $ (III) $

JamiaJamia 2011

Solution:

Ractivity decreases in the order $ allylic\text{ }halide>2{}^\circ \,aliphatic\text{ }halide $ $ >1{}^\circ aliphatic\text{ }halide. $