Q.
Arrange the following carbanions in order of their decreasing stability.
$\left(I\right) H_{3}C - C \equiv C^{-}$
$\left(II\right) H - C \equiv C^{-}$
$\left(III\right) H_{3}C - CH^{-}_{2}$
Hydrocarbons
Solution:
The order of decreasing stability of carbanions is:
$sp$-hybridised carbon atom is more electronegative than $sp^3$-hybridised carbon atom and hence, can accommodate the negative charge more effectively. $— CH_3$ group has $+I$ effect, therefore, it intensifies the negative charge and hence, destabilises the carbanion
