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Q. An organic compound contains $69\%$ carbon and $4.8\%$ hydrogen, the remainder being oxygen. What will be the masses of carbon dioxide and water produced when $0.20 \,g$ of this substance is subjected to complete combustion.

Organic Chemistry – Some Basic Principles and Techniques

Solution:

$\% C=\frac{12}{44}\times\frac{\text{mass of $CO_{2}$ formed}}{\text{mass of substance taken}}\times100$
$69=\frac{12}{44}\times\frac{\text{Mass of $CO_{2}$ formed}}{0.2}\times100$
$\therefore $ Mass of $CO_{2}$ formed $=\frac{69\times44\times0.2}{12\times100}=0.506\, g$
$\% H=\frac{2}{18}\times\frac{\text{mass of $H_{2}O$ formed}}{\text{mass of substance taken}}\times100$
$4.8=\frac{2}{18}\times\frac{x}{0.2}\times100$
$x=\frac{4.8\times18\times0.1}{100}$
$=0.086\,g$