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Q. An electric current of 0.965 ampere is passed for 2000 s through a solution containing $ {{[Cu{{(C{{H}_{3}}CN)}_{4}}]}^{+}} $ and metallic copper is deposits d at the cathode. The amount of Cu deposited is

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Solution:

$ {{[Cu{{(C{{H}_{3}}CN)}_{4}}]}^{+}}+{{e}^{-}}\xrightarrow[{}]{{}}Cu+4C{{H}_{3}}CN $ For the above reaction 1 F charge is required to deposit 1 mole of Cu (i.e. 63.5 g) Charge supplied $ =0.965\times 2000 $ $ =2\times 965=0.02\text{ }F $ $ \therefore $ Moles of Cu deposited = 0.02 mol