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Q. An amine $C_3H_9N$ reacts with benzene sulfonyl chloride to form a white precipitate which is insoluble in aq. $NaOH$. The amine is

WBJEEWBJEE 2014

Solution:

Since, the amine gives white precipitate with benzene sulphonyl chloride which is insoluble in aq. $NaOH$, so it must be a secondary amine (i.e., amine having RNHR group).
Among the given compound, only
image
is a secondary amine, so it represents the structure of given amine.