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Chemistry
Among the following, the group of molecules that undergoes rapid hydrolysis is
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Q. Among the following, the group of molecules that undergoes rapid hydrolysis is
NTA Abhyas
NTA Abhyas 2020
The s-Block Elements
A
$SF_{6},Al_{2}Cl_{6},SiMe_{4}$
10%
B
$BCl_{3},SF_{6},SiCl_{4}$
5%
C
$BCl_{3},SiCl_{4},PCl_{5}$
86%
D
$SF_{6},Al_{2}Cl_{6},SiCl_{4}$
0%
Solution:
$BCl_{3},SiCl_{4}$ and $PCl_{5}$ get radily hydrolysed to give orthoboric, orthosilicic and phosphoric acid respectively.
$BCl_{3}+3H_{2}O \rightarrow H_{3}BO_{3}+3HCl$
$SiCl_{4}+4H_{2}O \rightarrow H_{4}SiO_{4}+4HCl$
$PCl_{5}+H_{2}O \rightarrow POCl_{3}+2HCl\overset{H_{2} O \left(e x c e s s\right)}{ \rightarrow }H_{3}PO_{4}+HCl$