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Q. Among the following pairs those in which both species have similar structure are
(i) $N_3^-, XeF_2$
(ii) $[ICl_4]^-, [PtCl_4]^{2-}$
(iii) $[ClF_2]^+, [ICl_2]^-$
(iv) $XeO_3, SO_3$

Chemical Bonding and Molecular Structure

Solution:

(i) $N_3^- \to $ linear, $XeF_2\to$ linear
(ii) $ICl_4^- \to$ Square planar, $[PtCl_4]^{2-} \to $ Square planar
(iii) $ClF_2^+ \to$ Bent, $ICl_2^- \to$ linear
(iv) $XeO_3 \to $ Trigonal pyramidal, $SO_3\to$ Trigonal planar