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Chemistry
Among the following compounds, which one has the shortest C—Cl bond ?
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Q. Among the following compounds, which one has the shortest $C—Cl$ bond ?
JEE Main
JEE Main 2020
Haloalkanes and Haloarenes
A
$H_{3} C-Cl $
21%
B
22%
C
50%
D
6%
Solution:
In option $(3) C - Cl$ bond is shortest due to resonance of lone pair of $- Cl$.
Due to resonance $C - Cl$ bond acquire partial double bond character.
Hence $C - Cl$ bond length is least.