1. Tardigrade
  2. Question
  3. Chemistry
  4. Among (.i.)C6H5NH2 (.ii.)CH3NHCH3 (.iii.)(.CH3(.)2NCH3 and (.iv.) NH3, the correct order of basic strength follows the order

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Q. Among $\left(\right.i\left.\right)C_{6}H_{5}NH_{2}$ $\left(\right.ii\left.\right)CH_{3}NHCH_{3}$ $\left(\right.iii\left.\right)\left(\right.CH_{3}\left(\left.\right)_{2}NCH_{3}$ and $\left(\right.iv\left.\right)$ $NH_{3},$ the correct order of basic strength follows the order

NTA AbhyasNTA Abhyas 2022

Solution:

The aromatic amines are less basic than aliphatic amines.
$\left(\text{CH}\right)_{\text{3}} \left(\text{NHCH}\right)_{\text{3}} \, \text{>} \, \left(\left(\text{(CH}\right)_{\text{3}} \text{)}\right)_{\text{2}} \left(\text{NCH}\right)_{\text{3}} \, \text{>} \, \left(\text{NH}\right)_{\text{3}} \, \text{>} \, \left(\text{C}\right)_{\text{6}} \left(\text{H}\right)_{\text{5}} \left(\text{NH}\right)_{\text{2}}$