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Chemistry
All Cu (II) halides are known except the iodide. The reason for it is that
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Q. All $Cu$ (II) halides are known except the iodide. The reason for it is that
J & K CET
J & K CET 2011
The d-and f-Block Elements
A
iodide is a bulky ion
12%
B
$Cu^{2+}$ oxidizes iodide to iodine
46%
C
$Cu^{2+}_{(aq)}$ has much more negative hydration enthalpy
32%
D
$Cu^{2+}$ ion has smaller size
10%
Solution:
$2Cu^{2+} + 41^- \to 2CuI_2$
The $Cul_2$ immediately decomposes to liberate $I_2$ and insoluble copper$(I)$ iodide.
$2CuI_2 \to 2CuI + I_2$