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Q. A white solid $X$ on heating gives a white solid $Y$ and an acidic gas $Z$. Gas $Z$ is also given out when $X$ reacts with an acid. The compound $Y$ is also formed if caustic soda is left open in the atmosphere. $X$, $Y$ and $Z$ are
$X$ $Y$ $Z$
(a) $NaHCO_3$ $Na_2CO_3$ $CO_2$
(b) $Na_2CO_3$ $NaOH$ $CO_2$
(c) $Na_2CO_3$ $NaHCO_3$ $CO_2$
(d) $NaOH$ $NaHCO_3$ $CO_2$

The s-Block Elements

Solution:

$\underset{(X)}{2 NaHCO _3} \rightarrow \underset{(Y)}{Na _2 CO _3}+ \underset{(Z)}{CO _2}+ H _2 O$
$\underset{(X)}{NaHCO _3}+ HCl \rightarrow NaCl + \underset{(Z)}{CO _2}+ H _2 O$
$2 NaOH +\underset{\text { (atmosphere) }}{ CO _2} \rightarrow \underset{( Y )}{ Ca _2} Na _2+ H _2 O$