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Q. A volume of a gas at $ {{20}^{\circ}}C $ is $ 100\,c{{m}^{3}} $ at normal pressure. If it is heated to $ {{100}^{\circ}}C $ its volume becomes $125\, cm$ at the same pressure the volume coefficient of the gas will be normal pressure) :

Delhi UMET/DPMTDelhi UMET/DPMT 2001

Solution:

The volume coefficient is given by
$ \alpha =\frac{{{V}_{2}}-{{V}_{1}}}{{{V}_{1}}{{T}_{2}}-{{V}_{2}}{{T}_{1}}} $
Given, $ {{T}_{1}}={{20}^{\circ}}C,$
${{V}_{1}}=100\,c{{m}^{3}},$
${{T}_{2}}={{100}^{\circ}}C $ ,
$ {{V}_{2}}=125\,\,c{{m}^{3}} $
$ \Rightarrow \alpha =\frac{125-100}{(100\times 100)-(125\times 20)} $
$ =\frac{25}{10000-2500} $
$ =\frac{75}{7500}=0.0033{{/}^{\circ}}C $ .