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Q. A solution of an acid has pH = 4.70. Find out the number of $OH^-$ ions $(pK_w = 14)$

AIEEEAIEEE 2002Equilibrium

Solution:

$pH=4.70 \Rightarrow -log\left[H^{+}\right]=4.70$
$\therefore log \left[H^{+}\right]=-4.7=\bar{5}\cdot30$
or $\left[H^{+}\right]=1.999 \times10^{-5}=2\times10^{-5}$
$pK_{w}=14 \Rightarrow \left[H^{+}\right]\times\left[OH^{-}\right]=10^{-14}$
$\therefore \left[OH^{-}\right]=\frac{10^{-14}}{2\times10^{-5}}=0.5\times10^{-9}$
$=5\times10^{-10}$