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Q. A solution contains $Fe^{2+}, Fe^{3+}$ and $I^-$ ions. This solution was treated with iodine at $ 35^{\circ} C. E^{\circ}$ for $Fe^{3+} /Fe^{2+}$ is $+0.77 \, V$ and $E^{\circ}$ for $I_2/2I^- = 0.536 \, V.$
The favourable redox reaction is-

AIPMTAIPMT 2011Electrochemistry

Solution:

$2Fe^{=3} + 2I^- \rightarrow I_2 + 2Fe^{=2}$