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Q. A metal $M$ reacts with sodium hydroxide to give a white precipitate $X$ which is soluble in excess of $NaOH$ to give $Y$. Compound $X$ is soluble in $HCl$ to form a compound $Z$. Identify $M, X, Y$ and $Z$.
M X Y Z
(a)$\quad$ $Si$ $\quad$ $SiO_2$ $\quad$ $Na_2 SiO_3\quad$ $SiCl_4$ $\quad$
(b) $Al$$\quad$ $Al(OH)_3$ $NaAlO_2$ $AlCl_3$ $\quad$
(c) $Mg$$\quad$ $Mg(OH)_{3}$ $NaMgO_3$ $MgCl_2$ $\quad$
(d) $Ca$$\quad$ $Ca(OH)_2$ $Na_2CO_3$ $NaHCO_3$ $\quad$

The p-Block Elements

Solution:

$\underset{(M)}{2 Al }+2 NaOH +6 H _2 O \longrightarrow \underset{(X)}{2 Al ( OH )_3}+\xrightarrow[NaOH]{\text { Exess of }}\underset{( Y )} {NaAlO _2}$
$\underset{(X)}{2 Al ( OH )_3}+6 HCl \longrightarrow \underset{\text { (Z) }}{2 AlCl _3}+6 H _2 O$