For d-sub-shell, the value of azimuthal quantum number $ (l)=2. $ $ \therefore $ Total number of values of $ m=(2l+1)=5 $ These five values of m are -2, -1, 0, +1 and +2. Hence, 3d-electron can have -2 magnetic quantum number. (-3 and +3 values are possible only for f-orbitals)